First device on the IDE cable is set to master, the second to Slave
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the bottom of the drives should have some picture explaining how to set the jumpers for master, slave, and cable select. make sure your bios settings are also correct.
Well, I got another question. If I plug in DVD drive and HDD it boots the OS without ask me to boot from CD. But I want to boot from CD to reinstall windows, so if I boot only with DVD drive and plug in the HDD later the windows setup freezes every time I start it.